《高等院校“十一五”规划教材:物理化学简明双语教程》编写是为了适应物理化学双语教学这一全新的教学模式,解决物理化学双语教材短缺的问题。在编写的过程中尽量做到内容精练、简明易懂,并对每一部分重点内容均采用英、汉双语进行编写。《高等院校“十一五”规划教材:物理化学简明双语教程》共分十章,内容包括:气体的pVT性质;热力学第1定律;热力学第二定律;多组分系统热力学;化学平衡;相平衡;电解质溶液;电化学;界面现象;化学动力学。
《高等院校“十一五”规划教材:物理化学简明双语教程》既可作为高等院校双语物理化学教学的教材使用,也可以作为非双语物理化学教学的参考教材。
随着中国与世界的接轨和世界经济一体化的进程,迫切需要大量精通英语的人才。作为一种培养国际化人才的有效手段,双语教学势在必行。国家教育部也在2002年提出加强大学本科教学的12项措施中,要求各高校在三年内开设5%-10%的双语课,并引进原版教材和编写双语教材。
开设物理化学双语课,可以帮助学生扩大专业和非专业英语词汇量,提高学生的英语水平,开阔视野。原版物理化学教材一方面价格很昂贵,另一方面也不完全适合国内大学本科学生的学习。编写一套在效度、信度、难度各方面都符合教学要求的双语教材,不仅可以减少教师的备课难度和工作量,而且对激发学生专业学习的兴趣也大有帮助。这本《物理化学简明双语教程》对教学基本要求所规定的内容采用汉语和英语两种语言形式编写,便于教师和学生理解与学习。
本教材各章内容结构如下:第一章气体的pVT性质;第二章热力学第一定律;第三章热力学第二定律;第四章多组分系统热力学;第五章化学平衡;第六章相平衡;第七章电解质溶液;第八章电化学系统;第九章界面现象;第十章化学动力学。其中,第一至第六章主要由何美编写,第七至第十章主要由周华锋编写。此外,参与本书编写的还有侯纯明、张丽清、王雅静、李云等老师。
另外,为了与《物理化学简明双语教程》这一教材配套,我们还编写了物理化学双语解题指导:《物理化学双语基础》,以方便学生学习使用本教材。该解题指导已经由中国石化出版社出版发行。
由于编者水平有限,书中错误和不当之处在所难免,欢迎读者批评指正。
Introduction
0.1 Physical chemistry
0.1.1 Contents of physical chemistry
0.1.2 Issues to be solved by physical chemistry
0.1.3 Advice for studying physical chemistry
0.2 Indication and operation of physical quantity
0.2.1 Indication of physical quantity
0.2.2 Operation of physical quantity
Chapter 1 The pVT properties of gases
1.1 State equation of the perfect gas
1.1.1 Empirical law of gas
1.1.2 State equation of the perfect gas
1.1.3 Model of the perfect gas
1.2 Mixture of the perfect gas
1.2.1 Composition of perfect gas mixture
1.2.2 Dalton’S law of partial pressures
1.2.3 Amagat’S law of partial volumes
1.2.4 Mean molar mass of mixed gas
1.3 Liquefaction of real gas and critical properties
1.3.1 Saturated vapor pressure of liquid
1.3.2 Liquefaction of real gas and critical properties
1.4 State equations of real gas
1.4.1 The van der Waals equation
1.4.2 The virial equation of state
1.5 The law of corresponding states
1.5.1 Compression factors
1.5.2 The law of corresponding states。
EXERCISES
Chapter 2 The first law of thermodynamics
2.1 The basic concept of thermodynamics
2.1.1 System and surroundings
2.1.2 Extensive property and intensive property of system
2.1.3 State and state function of system
2.1.4 Equilibrium state of thermodynamics
2.1.5 Process and path
2.2 The first law of thermodynamics
2.2.1 Heat
2.2.2 Work
2.2.3 Calculation of volume work
2.2.4 Thermodynamic energy
2.2.5 The first law of thermodynamics.
2.3 The heat at constant volume.the heat at constant pressure and enthalpy
2.3.1 The heat at constant volume
2.3.2 The heat at constant pressure
2.3.3 Enthalpy.
2.3.4 Hess’s Law
2.4 Heat capacity
2.4.1 Heat capacity
2.4.2 Relation between Cp,mand P
2.4.3 Empirical formula between Cp,m and T
2.4.4 Relation between Cp,m and Cv,m
2.4.5 Joule experiment
2.5 Reversible process and equation of adiabatic reversible process of the perfect gas
2.5.1 Reversible process
2.5.2 Isothermal reversible process of the perfect gas.
2.5.3 Adiabatic reversible process of the perfect gas
2.6 Phase transformation process.
2.6.1 Phase and enthalpy of phase transition.
2.6.2 Calculation of AH of phase transformation process
2.7 Standard molar enthalpy of reaction
2.7.1 Chemical stoichiometric number
2.7.2 Extent of a reaction
2.7.3 Molar enthalpy of reaction
2.7.4 Standard molar enthalpy of reaction
2.8 Standard molar enthalpy of formation and standard molar enthalpy of combustion
2.8.1 Standard molar enthalpy of formation
2.8.2 Standard molar enthalpy of combustion
2.8.3 The temperature—dependence of A,n(T)一Kirchhoff’S formula.
2.8.4 The relation between Qp and Qv.
2.8.5 Maximum temperature of explosion and flame reaction
2.9 Throttling process and Joule—Thomson effect
2.9.1 Joule—Thomson experiment
2.9.2 Experiment result
2.9.3 Result analysis
2.9.4 Characteristice of throttling process
2.9.5 Joule-Thomson coefficient
EXERCISES
Chapter3 The Second Law of thermodynamics
Chapter4 The thermodynamics of multi-component systems
Chapter5 Chemical equilibrium
Chapter6 Phase equilibrium
Chapter7 Electrolyte solution
Chatper8 Electrochemical system
Chapter9 Interface phenomena
Chapter10 Chemical Kinetics
REFERENCE BOOKS